The main contributions of this thesis are three-fold. First, it develops a framework for evaluating the entity representations produced by MLMs using a document-level relation extraction (DLRE) setting. In this setting, each document can be represented by a KG that describes its contents according to some ontology. Possible subject-relation-object triples from each document are verbalized into candidate statements, then scored by a given MLM and ranked, where that ranking is analyzed in various ways. By changing only the input representations of the subject and object entities of these statements and keeping all else constant, the experimental framework enables experiments that look at the effects of changes to those representations. Second, the thesis presents two zero-shot methods for improving those entity representations relative to document contents, both of which do not update the underlying MLM in any way. These representations were evaluated on three DLRE datasets based on Wikipedia articles, news articles, and biomedical paper abstracts. In one case, general-domain MLMs that used these improved representations even performed better on biomedical data than biomedical-specific MLMs that did not use them. Finally, the thesis develops a procedure for modifying general-domain DLRE datasets to be adversarial by intentionally using well-known entities in unusual contexts. The thesis found that MLMs overwhelmingly favored their background knowledge rather than the text of a document when performing statement ranking, so this adversarial data served to ensure that any improvements on the statement-ranking task were due to MLMs correctly using the documents’ text. These contributions are implemented in the publicly-available software package LINTEXT.